If the system goes around the cycle in a counter-clock wise direction, does it absorb or liberate heat in one cycle ? What is the magnitude of the heat absorbed or liberates in one counterclockwise cycle ?
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Solution
As ΔU is a state function, thus ΔUcycle=0
Area enclosed by the cyclic process in P-V graph gives the work done by the gas during that cycle.
For the process to be in counter-clock wise direction, the work of expansion (a to b) is less than that of compression (b to a).
⟹ Net work done Wcycle<0
Using 1st law, Qcycle=ΔUcycle+Wcycle
∴Qcycle=0+Wcycle⟹Qcycle<0
Hence the system liberates heat.
As the magnitude of work done for the clock wise and anti-clockwide directions is same, thus the amount of heat liberated is also same i.e 7200 J