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Question

If the vapour pressure of solutions of two liquids are less than those expected from ideal solution they are said to have:

A
negative deviation from ideal behaviour
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B
positive deviations from ideal behaviour
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C
ideal behaviour
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D
positive deviation for lower concentration and negative deviations for higher concentration
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Solution

The correct option is A negative deviation from ideal behaviour
If the vapour pressure of solutions of two liquids are less than those expected from ideal solution there 1-2 interaction is higher than 1-1 and 2-2 interactions.
Hence, these types of solution show negative deviation from ideal behavior.


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