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Question

If the weight of 5.6 lit of a gas at NTP is 11g, the gas may be: (at. wt. of P=31,N=14.O=16 and Cl=35.5).

A
phosphine
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B
phosgene
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C
nitric oxide
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D
nitrous oxide
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Solution

The correct option is D nitrous oxide
Mass of the gas m=11gm
Volume occupied by the gas
=V=5.6l
NTP temperature of the gas =T=273K and pressure exerted by the gas =P=1atm
Gas=W=?
[ any gas can be identified by its molecular weight]
PV=mWRT
W=mRTPV.....(1)
Substituting the values from the data in equation (1), we get
W=11×0.0821×2731×5.6
W=11×22.45.6
W=11×4=44
Therefore, the gas can be either carbon dioxide, CO2 [or] nitrous oxide, N2O [or] propane, C3H3.

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