If the weight of 5.6 litres of a gas at S.T.P is 11 grams, the gas is:
A
Phosphine
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B
Phosgene
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C
Nitric oxide
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D
Nitrous oxide
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Solution
The correct option is C Nitrous oxide At S.T.P. 1 mole of a gas occupies a volume of 22.4 liters. Its mass will be equal to its molar mass. The weight of 5.6 liters of a gas at S.T.P is 11 grams. The weight of 22.4 litres of a gas at S.T.P will be 44 grams,
11g×22.45.6=44g The molar mass of nitrous oxide (N2O) is 14+14+16=44g/mol. Hence, the gas is nitrous oxide (N2O). Note: The molecular weight of phosphine PH3, phosgene COCl2 and nitric oxide NO are 34 g/mol, 99 g/mol and 30 g/mol respectively.