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Question

If there are 3 moles of atoms present in the packing of pattern ABC ABC ABC. What is the number of moles of tetrahedral voids?

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Solution

ABC ABC type of packing pattern is present in FCC unit cell.
Zeff=4
No. of moles of unit cell=34=0.75
No. of tetrahedral void present in one unit cell=8
Total no. of tetrahedral voids in 0.75 mole unit cell= 0.75×8
=6 moles of tetrahedral voids

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