If there are intramolecular H bonding in a compound then would there be intermolecular H bonding present between two of those compounds( Is it possible to have intra and intermolecular H bonding present in the same compound) for eg. in O nitrophenol will it have intermolecular H bonding prestn along with Intramolecular H bonding

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Q. Ortho-nitrophenol is steam volatile whereas para-nitrophenol is not. This is due to

1.

Intramolecular hydrogen bonding present in ortho-nitrophenol

2.

Intermolecular hydrogen bonding present in para-nitrophenol

3.

Intramolecular hydrogen bonding present in para-nitrophenol

4.

Inter-molecular hydrogen bonding present in ortho-nitrophenol.

Q. Nonpolar intramolecular and intermolecular bonds are present in:

Q. Assertion :Boiling point of p-nitrophenol is greater than that of o-nitrophenol. Reason: There is intramolecular hydrogen bonding in p-nitrophenol and intermolecular hydrogen bonding in o-nitrophenol.

Q. Assertion (A):

H_{2} O

is liquid while

H_{2} S

is a gas at room temperature.
Reason (R):

H_{2} O

has intermolecular hydrogen bonding while H-bonds are absent in

H_{2} S

Question 34.1

Structures of molecules of two compounds are given below.

Which of the two compounds will have intermolecular hydrogen bonding and which compound is expected to show intramolecular hydrogen bonding?

(ii) The melting point of the compound depends on, among other things, the extent of hydrogen bonding. On this basis explain which of the above two compounds will show higher melting point?

(iii) The solubility of compounds in water depends on power to form hydrogen bonds with water. Which of the above compounds will form a hydrogen bond with easily and be more soluble in it?

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