Since, ΔABC∼ΔDEF, then,
∠A=∠D,∠B=∠E,∠C=∠F
It is given that ∠A=45∘ and ∠E=56∘. As, ∠E=56∘, then, ∠B=56∘.
It is known that the sum of the angles of a triangle is 180∘, therefore,
∠A+∠B+∠C=180∘
∠C=180∘−(∠A+∠B)
=180∘−(45∘+56∘)
=79∘