If â–³Hvapourisation of substance X(l) (molar mass = 30 g/mol) is 300 J/g at its boiling point 300 K, molar entropy change for reversible condensation process is:
A
30J/molK−1
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B
−60J/molK−1
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C
−30J/molK−1
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D
None of these
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Solution
The correct option is C−30J/molK−1 Vapourisation and condensation are reversible process,
Enthalpy of vapourisation = 300J/g
Enthalpy of condensation = −300J/g
Molar enthalpy of condensation = −300×30g/mol
Molar entropy, △S=△HcondensationT △S=−300×30300 =−30J/molK−1