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NO2 interferes in the 'ring test' of NO3. A chemical method of removal of NO2 is boiling the mixture with NH4Cl.
NO2 is decomposed as follows:
NaNO2+NH4ClNaCl+N2+2H2O

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Solution

NO2 interferes in the ring test of NO3.
To remove NO2 from the solution, it is boiled with ammonium chloride solution.
NO2 decomposes to nitrogen. The reaction is as follows:
NaNO2+NH4ClNaCl+N2+2H2O

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