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Dipole Moment

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Question

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The presence of polar bonds in polyatomic molecules suggests that the molecule has non-zero dipole moment.
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Solution

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Presence of lone pair may cancel the effects of polar bonds. This may lead to overall zero dipole moment.

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Presence of lone pair on central atom of a molecule although ignored in the identification of shape of molecule but they distort the shape of a molecule so as to reduce lone pair-bond pair repulsion.

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