If we pump methane gas into a closed gas cylinder containing chlorine gas, the chlorine gas will substitute the hydrogen in methane.
False
Chlorine replaces hydrogen in methane very quickly in the presence of sunlight.
CH4(g)+Cl2(g)→CH3Cl(g)+HCl(g) (in the presence of sunlight)
Since the cylinder is closed, no sunlight will enter the cylinder and hence chlorine will not substitute the hydrogen in methane.