The correct option is C [0,∞)
We have,
x2+4y2+9z2−6yz−3xz−2xy
=x2+(2y)2+(3z)2−(x)(2y)−(2y)(3z)−(3z)(x)
=12[2x2+2(2y)2+2(3z)2−2(x)(2y)−2(2y)(3z)−2(3z)(x)]
=12[(x−2y)2+(2y−3z)2+(x−3z)2]
(x−2y)2, (2y−3z)2, (x−3z)2 are positive as square of real numbers are always positive. So,
x2+4y2+9z2−6yz−3xz−2xy is always positive
Therefore, range is [0,∞)