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Question

If you are given Avogadro's number of atoms of a gas X. If half of the atoms are converted into X+(g) by energy ΔH. The IE of X is :

A
2ΔHNA
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B
2NAΔH
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C
ΔH2NA
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D
NAΔH
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Solution

The correct option is A 2ΔHNA
Given no. of atoms = Avogadro's no. of atoms = NA=6.023×1023
Given that NA2 atoms are ionized, i.e.,
Ionization energy of NA2 atoms of gas X = ΔH
Ionization energy of 1 atom of gas X = ΔH(NA2)=2.ΔHNA
Hence, Ionisation energy of gas X is 2.ΔHNA.

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