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Question

In a 2.5 L flask at 27C temperature, the pressure of a gas was found to be 8 atm. If 2.41×1023 molecules of the same gas are introduced into the container, the temperature changed to T2. The pressure of gas is found to be 10 atm. Find out the value of T2:

A
253 K
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B
347 K
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C
230 K
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D
370 K
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Solution

The correct option is B 253 K
6.023×1023 molecules corresponds to 1 mole
2.41×1023 molecules corresponds to =2.41×10236.023×1023=0.4 moles
Case (i)
P1V1=n1R1T1
8(2.5)=n1(0.08)(300)
n1=8(2.5)(0.08)(300)=0.833 moles
Total moles n2=0.833+0.4
n2=1.233
Case (ii)
P2V2=n2RT2
10(2.5)=1.233(0.08)T2
T2=253.4

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