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Question

In a base-catalyzed elimination reaction, the base takes away a proton from the β position of the leaving group (the group that goes away with the bonding pair of electrons) and a double bond is formed. When the base is bulky it prefers to take away the proton from the less hindered position.
In the above process, Y and Z are:
884969_a1a27c5e99d64bd982a2c5e4861f3878.jpg

A
two molecules of ethanal
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B
propanal and ethanol
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C
propanoic acid and carbon dioxide
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D
propanal and methanal
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Solution

The correct option is C propanal and methanal
The dehydrobromination of 2-bromobutane in presence of bulky base gives 1-butene as major product. Reductive ozonolysis of 1-butene gives propanal and methanal.
821141_884969_ans_cad647c8b50f487d9edd96894a8225ee.png

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