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Question

In a basic medium, H2O2 exhibits which of the following reactions?
A.Mn2+Mn4+
B. I2I
C. PbSPbSO4

A
(A), (C) only
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B
(A) only
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C
(B) only
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D
(A), (B) only
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Solution

The correct option is D (A), (B) only
In basic medium, oxidising action of H2O2.
Mn2++H2O2Mn+4+2OH

In basic medium, reducing action of H2O2.
I2+H2O2+2OH2I+2H2O+O2

In acidic medium, oxidising action of H2O2.
PbS(s)+4H2O2(aq)PbSO4(s)+4H2O(l)

Hence, option (d) is correct.

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