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Question

In a calorimeter of water equivalent 20 g, water of mass 1.1 kg is taken at 288 K temperature. If steam at temperature 373 K is passed through it and temperature of water increases by 6.5 C, then the mass of steam condensed is
[Take, s=1 cal/ C g, L=540 cal/g ]

A
17.5 g
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B
11.7 g
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C
15.7 g
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D
18.2 g
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Solution

The correct option is B 11.7 g
The water equivalent of calorimeter is 20 g.

Initially, the temperature of water of mass 1.1 kg is,

Ti=288 K=288273=15C


Let the mass of steam that get condensed, when it passes through water at 15 C be x g.

Heat released by steam,

Qreleased=mL+msΔT

Qreleased=(x×540)+[x×1×(100156.5)]

Qreleased=540x+78.5x ......(1)

The heat released by the steam goes to the water-calorimeter system.

Heat gained by water,

QW=msΔT=1100×1×6.5

QW=7150 cal

Similarly, heat gained by calorimeter,

QC=msΔT=20×1×6.5

QC=130 cal

From energy conservation,

Qreleased=Qabsorbed

540x+78.5 x=7150+130

618.5 x=7280

x=7280618.5=11.77 g

<!--td {border: 1px solid #ccc;}br {mso-data-placement:same-cell;}--> Hence, (C) is the correct answer.

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