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Question

In a closed system A(s) gives 2B(g) +3C (g) if the partial pressure of c is doubled then the partial pressure of b will be

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Solution

For the reaction, the equilibrium constant is given by K = [PC]3x[PB]2 as A is a solid, its pressure is not counted so when thepressure of C is doubled, the new K' = 8x[PC]3x[P'B]2 this has to be neutralized by decreasingPB so that the value of K becomes the previous value. equating both equations [PC]3x[PB]2= 8x[PC]3x[P'B]2 hence[P'B]2=[PB]2/8 hence[P'B] =[PB]/2√2

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