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Question

In a collection of H-atoms, all the electrons jump from n=5 to the ground level (directly or indirectly) without emitting any line in the Balmer series. The number of different possible radiations is:

A
10
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B
8
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C
7
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D
6
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Solution

The correct option is D 6
Maximum number of spectral lines (N) corresponding to transition from n1=5 to n2=1 are:
N= number of lines emitted =12(n1n2)(n1n2+1)
=12(51)(51+1)
=10
But the emissions in Balmer series aren't taking place. So, the transitions ending at and beginning from n=2, are not possible.
Therefore,four(52,42,32 and 21) such transitions aren't possible.
Number of possible transitions =6

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