In a compound, oxide ions have a cubic close packing arrangement. Cations A are present in half of the tetrahedral voids and cation B occupies the octahedral voids. The simplest formula of the compound is:
A
AB2O4
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B
A2BO4
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C
ABO2
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D
ABO
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Solution
The correct option is DABO There are 4 oxide ions per unit cell here. Tetrahedral voids = 2× number of oxide ions = 8 Number of 'A' ions = half the tetrahedral voids, 4 ions Octahedral voids = number of oxide ions = 4 Number of 'B' ions = all the octahedral voids, 4 ions A4B4O4=ABO