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Question

In a constant volume calorimeter, 3.5 g of a gas with molecular weight 28 was burnt in excess oxygen at 298.0 K. The temperature of the calorimeter was found to increase from 298.0 K to 298.45 K due to the combustion process. Given that the heat capacity of the calorimeter is 2.5kJK1, find the numerical value for the enthalpy of combustion of the gas in kJmol1.

A
9
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B
5
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C
3
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D
2
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Solution

The correct option is A 9
Number of moles of gas = 3.528=0.125
Heat evoled = Heat capacity ×T
= 2.5 × (298.45 - 298)
= 2.5 × 0.45 = 1.125 kJ
Heat eveloved per mole = 1.1250.125=9kJ

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