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Question

In a cubical vessel are enclosed n molecule of a gas each having mass 'm' and an average speed 'v'. if l is the length of each edge on the cube, the pressure exerted by the gas will be

A
nmv2l3
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B
nm2v2l3
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C
mnv23l3
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D
nmv2l
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Solution

The correct option is C mnv23l3
The momentum imparted per unit time to the wall by molecule will be
ΔF=nΔp
so change in momentum will beΔp =2mvx
and molecule will collide form the two surfaces of wall so total time Δt =2Lvx
so number of collision by molecule in unit time will be n =1Δt =vx2L
so F =mv2xL
now for cube all the direction are equivalent,we have
F=mnv23ln(i.e v2n=v2 it is the sum of three velocity in x,y,z direction)
so pressure p=Fl2
p=mnv23l3

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