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Question

In a hydrocarbon, mass ratio of hydrogen and carbon is 1:3, the empirical formula of hydrocarbon is :

A
CH4
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B
CH2
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C
C2H
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D
CH3
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Solution

The correct option is A CH4
Mass ratio of C:H=3:1
As, molar mass ratio of C:H=12:1
Now, ratio of mass ratio and molar mass ratio is :
Massratio(CandH)Molarmassratio(CandH)=3:112:1=3:12=1:4 (CandH)
Therefore, for every C atom, there are 4 H atoms, hence empirical formula =CH4.

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