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Question

In a hydrogen atom, in transition of electron a photon of energy 2.55 eV is emitted, then calculate change in wavelength of the electron.

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Solution

Let the energy of photon is
ΔE=2.55eV=2.55×1.602×1019J
The wavelength of the photon of light is
λ=hcΔE=6.62×1034×3×1082.55×1.602×1019m=4861A0
This corresponds to the second line Balmar series.
The transition is n2=4n1=2
The change in the wavelength of the electron is
Δλ=hmu4hmu2=hm(u4u2)=6.626×10349.1085×1031(422.19×10m/s)=6.64A0.

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