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Question

In a mildly alkaline medium, thiosulphate ion is oxidized by KMnO4 to "A". The oxidation state of sulphur in "A" is:

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Solution

In a mildly alkaline medium, thiosuphate is quantitavely oxidized by KMnO4 to SO24
8MnO4+3S2O23+H2O8MnO2+6SO24+2OH

"A" SO24

Oxidation number of S=+6.


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