In a reaction, 358 g of TiCl4 is reacted with 96 g of Mg. Calculate the % yield of Ti if 32 g of Ti is obtained from the reaction. (Molar mass of Ti = 48 g/mol, Mg = 24 g/mol)
A
35.46%
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B
66.86%
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C
85.76%
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D
48.34%
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Solution
The correct option is A 35.46% TiCl4+2Mg→2MgCl2+Ti Moles of TiCl4=358190=1.88; moles of Mg =9624=4 Calculation of limiting reagent: 2 moles of Mg reacts with 1 mole of TiCl4 4 moles will react =12×4=2 moles of TiCl4 Hence TiCl4 is the limiting reagent. 1 mole of TiCl4 produces 1 mole of Ti 1.88 mole will produce 1.88 mole of Ti Mass of 1.88 mole of Ti=1.88×48=90.24 g % yield =actual yieldtheoretical yield×100=3290.24×100=35.46