In a SN2 substitution reaction of the type-R-Br - Cl- R-Cl-Br-which one of the following has the highest relative rate-

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Chemical Properties of Alcohol

In a SN2 subs...

Question

In a $S_{N} 2$ substitution reaction of the type:
$R - B r + C l^{-} D M F - -- \to R - C l + B r^{-}$
which one of the following has the highest relative rate?

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C H_{3} C H_{2} B r

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C H_{3} C H_{2} C H_{2} B r

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Solution

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S_{N} 2

R - B r + C N^{-} D M F - -- \to R - C N + B r^{-}

R - B r + C l^{-} D M F - -- \to R - C l + B r^{-}

S_{N} 2

S_{N} 2

C l - C H_{2} - C H_{2} - B r

N \equiv C - C H_{2} - B r

C H_{3} - C H | B r - C H_{3}

C H_{3} - C H_{2} - B r

H C l

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