In a set of reactions of propionic acid yielded a compound D- CH3CH2COOH SOCl2- BNH3- C D The structure of D would be-

The correct option is D CH_3CH_2NH_2 (A)CH_3CH_2COOH(B)CH_3CH_2COCl(C)CH_3CH_2CONH_24KOH + Br_2→ (D)ethyl amine CH_3CH_2NH_2 The reaction is Hofman ...

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Byju's Answer

Standard XII

Chemistry

Curtius and Hofmann Rearrangements

In a set of r...

Question

In a set of reactions of propionic acid yielded a compound $D$ . $C H_{3} C H_{2} C O O H S O C l_{2} \to B N H_{3} \to C K O H - -- \to B r_{2} D$
The structure of $D$ would be:

C H_{3} C H_{2} C H_{2} N H_{2}

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C H_{3} C H_{2} C O N H_{2}

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C H_{3} C H_{2} N H C H_{3}

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C H_{3} C H_{2} N H_{2}

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Solution

The correct option is D $C H_{3} C H_{2} N H_{2}$
$C H_{3} C H_{2} C O O H (A) S O C l_{2} - ------ \to - S O_{2}, - H C l C H_{3} C H_{2} C O C l (B) N H_{3} - -- \to - H C l C H_{3} C H_{2} C O N H_{2} (C) 4 K O H + B r_{2} \to (D) C H_{3} C H_{2} N H_{2} e t h y l a m i n e$

The reaction is Hofmann bromamide reaction.

Option D is correct.

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C H_{3} C H_{2} C O O H S O C l_{2} - --- \to B N H_{3} - -- \to C K O H - -- \to B r_{2} D

The structure of D would be:

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In a set of reactions of propionic acid yielded a compound D. CH3CH2COOHSOCl2→BNH3→CKOH−−−→Br2D The structure of D would be:

The correct option is D CH3CH2NH2CH3CH2COOH(A)SOCl2−−−−−−−→−SO2,−HClCH3CH2COCl(B)NH3−−−→−HClCH3CH2CONH2(C)4KOH+Br2→(D)CH3CH2NH2ethylamineThe reaction is Hofmann bromamide reaction.Option D is correct.

In a set of reactions of propionic acid yielded a compound $D$ . $C H_{3} C H_{2} C O O H S O C l_{2} \to B N H_{3} \to C K O H - -- \to B r_{2} D$
The structure of $D$ would be: