In a thermodynamic process helium gas obeys the law TP−25=constant. If temperature of 2 moles of the gas is raised from T to 3T, then
Heat given to the gas is zero
Increase in internal energy is 6RT
Work done by the gas is - 6RT
TP−25=constant
∴(PV)P−25=constant
or PV53=constant
Comparing with the equation,
PVx=constant
We have x=53
Molar heat capacity of equation (1) is given by
C=Cv+R1−x
=32R+R1−53=0
∴Q=nCΔT=0
ΔU=−W
=nCvΔT
=(2)(32R)(3T−T)
=6RT