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Question

In a thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed by the gas is given by TΔX, where T is temperature of the system and ΔX is the infinitesimal change in a thermodynamic quantity X of the system. For a mole of monatomic ideal gas X=32Rln(TTA)+Rln(VVA). Here, R is gas constant, V is volume of gas, TA and VA are constants.

The List-I below gives some quantities involved in a process and List-II gives some possible values of these quantities.

List-I List-II
(i)

Work done by the system in process 123

(P)

13RT0ln2

(ii)

Change in intermal energy in process 123

(Q)

13RT0

(iii)

Heat absorbed by the system in process 123

(R)

RT0

(iv)

Heat absotbed by the system in process 12

(S)

43RT0

(T)

13RT0(3+ln2)

(U) 56RT0


If the process carricd out on one mole of monoatomic ideal gas is as shown in figure in the PV-diagram with P0V0=13RT0, the correct match is,


A

1Q,IIR,IIIS,IVU

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B

IQ,IIS,IIIR,IVU

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C

IS,IIR,IIIQ,IVT

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D

IQ,IIR,IIIP,IVU

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Solution

The correct option is A

1Q,IIR,IIIS,IVU


Degree of freedom f=3
(i) Work done in any process = Area under PV graph
Work done in 123=PoVo
=RTo3 ,hence for (i) the correct option is Q

(ii) Change in internal energy 123
ΔU=nCVΔT
=f2nRΔT
=f2(PfVfPiVi)
=32(3Po22VoPoVo)
=3PoVo, hence ΔU=RTo, the correct option is R
(iii) Heat absorbed in 123
for any process, 1st law of thermodynamics
ΔQ=ΔU+W
ΔQ=RTo+RTo3
ΔQ=4RTo3, hence the correct option is S
(iv) Heat absorbed in process 12
ΔQ=ΔU+W
=f2(PfVfPiVi)+W

=32(Po2VoPoVo)+PoVo

=52PoVo

=52(RTo3)
ΔQ=5RTo6, hence option U is correct

The correct option matches with 1Q,IIR,IIIS,IVU

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