In a Vander waals interaction: U=U0[(R0r)12−2(R0r)6]
A small displacement x is given from equilibrium position r=R0. Find the approximate PE function.
U=U0[(R0R0+x)12−2(R0R0+x)6]=U0⎡⎢ ⎢ ⎢⎣R120R120⎡⎢ ⎢ ⎢⎣11+xR0⎤⎥ ⎥ ⎥⎦12⎤⎥ ⎥ ⎥⎦−2⎡⎢ ⎢ ⎢⎣R0R0⎡⎢ ⎢ ⎢⎣11+xR0⎤⎥ ⎥ ⎥⎦6⎤⎥ ⎥ ⎥⎦=U0⎡⎢ ⎢ ⎢⎣⎡⎢ ⎢ ⎢⎣11+xR0⎤⎥ ⎥ ⎥⎦12−2⎡⎢ ⎢ ⎢⎣11+xR0⎤⎥ ⎥ ⎥⎦6⎤⎥ ⎥ ⎥⎦=U0[(1+xR0)−12−2(1+xR0)−6]=U0[[1−12xR0+66x2R20]−2(1−6xR0+15x2R20)]=36U0R20x2−U0