In an acidic buffer the ratio [acid]/[salt] is 0.5. If we make the concentration of acid, twice of its initial value then what is value of 10ΔpH.[log2=0.3]
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Solution
For acidic buffer, pH=pKa+log[S][A]Given, ratio of [acid]/[salt] is 0.5Hence, , Ratio of [salt]/[acid] is 2pH=pKa+log2 Now we doubled the concentration of acid. So [S][A]=1 pH=pKa+log1pH=pKa∴ΔpH=pKa+log2−pKa=log2=0.3∴10ΔpH=3