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Question

In an acidic buffer the ratio [acid]/[salt] is 0.5. If we make the concentration of acid, twice of its initial value then what is value of 10 ΔpH. [log2=0.3]

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Solution

For acidic buffer,
pH=pKa+log[S][A]Given, ratio of [acid]/[salt] is 0.5Hence, , Ratio of [salt]/[acid] is 2pH=pKa+log2
Now we doubled the concentration of acid. So [S][A]=1
pH=pKa+log1pH=pKaΔpH=pKa+log2pKa =log2=0.310ΔpH=3

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