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Question

In an exothermic reaction, heat is evolved, and system loses heat to the surrounding. For such system

A
qp will be negative
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B
rH will be positive
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C
qp will be positive
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D
rH will be negative
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Solution

The correct option is D rH will be negative
For exothermic reaction, enthalpy change is negative(rH is a negative).

qp=rH at constant pressure

qp will also be negative

Since in the question it is mentioned that it is an exothermic reaction.

qp=rH=negative value

So, options (A) and (B) are correct.

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