The law of constant proportion is also known as the law of definite proportion. This law states that in a compound, the elements are always present in definite proportions by mass. The reaction between copper and oxygen leading to the formation of copper oxide is written as follows
2Cu + O2 → 2CuO
As per the given data, 4.90 g of copper oxide was obtained from 3.92 g of copper. Therefore, the percentage of copper in 4.90g of CuO will be
= (mass of copper / mass of CuO) X 100
= (3.92 / 4.9) X 100
= 80 %
As per the data of the second experiment, 3.64g of copper is obtained from 4.55g of CuO. So, percentage of copper in this sample of copper oxide will be
= (mass of copper / mass of CuO) X 100
= (3.64 / 4.55) X 100
= 80 %
Thus, we see that percentage of copper in both samples of CuO is the same. This means that copper and oxygen always combine in a fixed ratio by mass to form CuO. Thus the law of constant proportions is satisfied here.