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Question

In an insulated vessel, 0.05 kg steam at 373 K and 0.45 kg of ice at 253 K are mixed. Then, find the final temperature of the mixture.
Given, Lfusion=80cal/g=336J/g,
Lvaporization=540cal/g=2268J/g,
Sice=2100J/kgK=0.5cal/gK and
Swater=4200J/kgK=1cal/gK

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Solution

Σθ=0
Heat lost by steam to convert into water at 0oC
HL=0.05×540+0.05×100×1=27+5=32Kcal
Heat required to change ice into 0oC water.
Hg=0.45×0.5×20+0.45×80=4.5+36=40.5Kcal

Released heat is less than the required heat so final temperature is 0oC of the mixture.

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