In basic medium CrO2−4 oxidizes S2O2−3 to form SO2−4 and itself changes into Cr(OH)−4. The volume of 0.154MCrO2−4 required to react with 40mL of 0.25MS2O2−3 is ______ mL.
(Rounded off to the nearest integer)
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Solution
+6CrO2−4++2S2O2−3→+3Cr(OH)−4++6SO2−4
Accodrding to law of equivalence, Milliequivalents of CrO2−4=Milliequivalents of S2O2−30.154×VCrO2−4×|6−3|=0.25×40×|2(6−2)|∴VCrO2−4=173mL