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Question

In basic medium CrO24 oxidizes S2O23 to form SO24 and itself changes into Cr(OH)4. The volume of 0.154 M CrO24 required to react with 40 mL of 0.25 M S2O23 is ______ mL.
(Rounded off to the nearest integer)

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Solution

+6CrO24++2S2O23+3Cr(OH)4++6SO24
Accodrding to law of equivalence,
Milliequivalents of CrO24=Milliequivalents of S2O230.154×VCrO24×|63|=0.25×40×|2(62)| VCrO24=173 mL

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