In beta decay, an electron, e− (or a positron, e+) is emitted by a nucleus. What happens to the atom, among the following options?
Writing down an example of β− decay,
14 6C→14 7N+e−+¯v,
we'll see, if you work the numbers,
mass(14 6C) > mass(14 7N+e−+¯v,)
where mass(14 6C) refers to the mass of the nucleus and not the atom. This is true for every β decay process. There is a Δm that predominantly becomes the kinetic energy (Δmc2)
of the outgoing electron (or positron).
The atomic energy levels are usually of the order of few tens of eV but the kinetic energy of the outgoing electron (or positron) is usually of the order of MeV. The electron (or positron) is too fast/energetic to be recaptured by the new atom of a higher atomic number.
Thus in β− decay, where the atom gets a new proton in the nucleus but is short of an electron to balance the extra charge, it becomes a positive ion; similarly, a β+ decay leaves an atom negatively charged, since a proton turns into a neutron.