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Question

In Boyles law experiment the graph drawn between pressure and density for a given temperature of different gases are the straight lines then the molecular weights have the relation


24871_b5d7278e83d6496781ffbd7afb48bb1f.png

A
M1>M2
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B
M2>M1
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C
M1=M2
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D
M22=M1
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Solution

The correct option is A M1>M2
First we derive an expression for density of a gas.
Density = mass(w)volume(V)
but we know that PV = nRT
now n = wM where M is molecular weight
So, PV = wMRT
this gives wV=PMRT = density = d
clearly graph of pressure vs density is a straight line with slope = RTM
steeper the line, more is the slope and so less is the mass (at a given temperature)
so here M1>M2

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