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Question

In BrF3, expected geometry is trigonal bipyramidal and actual geometry is T-shaped.

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Solution

BrF3 is AX5 type of molecule with 2 lone pairs and 3 bond pairs of electrons. The central Br atom undergoes sp3d hybridization. The expected geometry is trigonal bipyramidal and actual geometry is T-shaped since 2 of the orbitals are occupied by lone pairs.
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