In brown ring test, a freshly prepared ferrous sulphate solution is used because:
Ferrous sulphate when exposed to atmosphere oxidizes to ferric sulphate.
Ferric sulphate doesn't give a brown ring.
In brown ring test, a freshly prepared ferrous sulphate solution is used because on exposure to the atmosphere , it oxidizes to ferric sulphate which will not give brown ring.
12FeSO4+3O2−>4Fe2(SO4)3+2Fe2O3