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Question

In certain temprature compound AB2(g) dissociates according to the reaction
2AB2g2AB(g)+B2(g)
With degree of dissociation α, which is small compared with unity. The expression of KP, in terms of α and initial pressure P is:

A
Pα32
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B
Pα23
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C
Pα33
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D
Pα22
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Solution

The correct option is A Pα32
2AB2(g)2AB(g)+B2(g)
P 0 0
P(1α) Pα Pα2
Kp=(Pα)2.(Pα2)(P(1α))2,1α<<1
Kp=Pα32

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