Let the particle be moving around a circular path of constant radius r. If it speeds up or slows down, its motion is non-uniform and both the angular speed (ω) and the linear speed (v) change with time. Thus, at any instant, ω , v and r are related as :
v=ωr
Hence, the angular acceleration of the particle is given by,
α=dωdt
and the tangential acceleration at is given by,
at=dvdt=d(ωr)dt=rdωdt [because r is a constant]
Thus, at=αr.