In ΔABC it is given that ∠C=60o and ∠C>∠B.
Let us suppose that ∠C is just greater than ∠B and that ∠B is equal to 59o.
Then, the mesure of ∠A would be equal to "(180o−60o+59o)", which is equal to 61o.
So, in any case ∠A would be greatest of all the angles in the triangle.
We know, in a triangle, side opposite to the larger (greater) angle is longer.
The side opposite to ∠A is BC.
Hence,BC is the longest side of triangle ABC.