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Question

In electrolyte concentration cell:

A
the electrode material and the solution in both half-cells are composed of the same substances
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B
only the concentrations of solutions of the same substances is different
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C
Ecell=0
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D
the Nernst equation reduces to Ecell=(0.0591n)logQ at 25C
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Solution

The correct options are
A the electrode material and the solution in both half-cells are composed of the same substances
B only the concentrations of solutions of the same substances is different
C the Nernst equation reduces to Ecell=(0.0591n)logQ at 25C
D Ecell=0
For a concn cell
Eocell=0Keq=1
Cell rep. for example
Pt(s)|H2(g)|HCl(aq)|H2(g)|Pt(s)P1CP2
Ecell=00.0591nlogQ at 25

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