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Question

In FCC how many atoms are at a distance of 23r (where r is radius of atom) from a corner atom?

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Solution

For fcc lattice, a=22r (Where a is the side length)
23r=32a

If we want to find the distance between a corner atom and the face center atoms of the faces which are not touching that corner atom (let's say, XT) then,
XT2=TZ2+XZ2
Again, XZ2=XY2+YZ2=(a2)2+a2=5a24
So, XZ2=(a2)2+5a24=6a24
XZ=32a
So there will be 3 face center atoms which are at a distance 32a from a particular corner atom and again that corner atom will be shared by 8 cubes.
So, the total number of atoms that are at a distance 23r (where r is radius of atom) from a corner atom will be 8×3=24

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