In glycolysis, during oxidation electrons are removed by:
Glycolysis is a multi-step process that takes place in the cytoplasm, in which glucose (a six carbon sugar) is split into two molecules of the three-carbon sugar pyruvate with the generation of two molecules of ATP and two "high energy" electron carrying molecules of NADH.
In the pay-off stage of glycolysis, NAD+ accepts electrons from triose phosphate (Glyceraldehyde-3-phosphate).
Molecular oxygen is the final electron acceptor in the ETC, which helps generate a proton gradient for the synthesis of ATP.