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Question

In group 13, electronegativity first decreases from B to Al and then increase marginally down the group. This is because of :

A
non- metallic nature of B
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B
discrepancies in atomic size of element
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C
ability of B and Al to form pπ - pπ multiple bonds
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D
irregular trend in electronegativity throughout the periodic table
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Solution

The correct option is B discrepancies in atomic size of element
Answer:- (B) discrepancies in atomic size of an element.
Reason:-
Electronegativity of an element depends upon
(a) Size of an atom
(b) The magnitude of a nuclear charge
On going from Al to Ga, The electrons start filling into the d-subshells. Since these intervening electrons do not screen the nuclear charge.
Hence, the electrons in Ga experience more force of attraction than in Al causing a decrease in atomic size and increase in electronegativity.
Thus, Electronegativity decreases from B to Al and then increases due to discrepancies of an atomic size of the elements.

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