Mark a particular face X. (Later on, we will have to divide whatever answer we get by 6 because all 6 faces are identical at this point, and we have chosen one out of 6 randomly). Put a color on face X. There are 6 ways to do this.
Put another color on the face opposite X. There are 5 ways to do this.
Arrange the remaining 4 colors in the remaining four places - there are 3! ways to do this (circular permutation of 4 colours = (4-1)!
Total =[6.5.3!6
= 30