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Question

In isoelectronic series, which of the following will be the smallest?

A
O2
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B
F1
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C
Ne
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D
Na1+
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E
Mg2+
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Solution

The correct option is B Mg2+
Since, the number of electrons are same, size is determined by the number of protons. The atom with greatest nuclear charge pulls the electrons closer, thus, is the smallest.
The O2 has 8 protons and the nuclear charge is the smallest of the series. Thus, it has the least "pull" on the electrons and this species is the largest.
Mg2+ has 12 protons and the nuclear charge is highest and thus this will be the smallest.

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